Scott, the best way to prevent these types of attacks is to follow our recommended antispam settings. SPF/RDNS/DKIM/DMARC will all help cut back on the amount of phishing messages received by your end users as the SmarterMail instance will be capable of verifying the from domains. Our recommended settings can be found here:
Kyle Kerst
IT Coordinator
SmarterTools Inc.
www.smartertools.com