So, the problem is now resolved,
Apparently this is a rather common problem with outlook that you can get email but not send. After a google search and reading through dozens of other posting the same problem, problem solved, One guy posted that he was using the computers, they had a storm, lost power, and after power was restored, outlook would receive, but no longer send.
So, the only conclusion to that is corrupted files.
Turns out, each time we exited outlook, it would forget that you just changed the password, and revert back to the old password.
Solution :
1) In Outlook, made an archive file of all of the email for the user account.
2) Exit outlook and then restart outlook Confirmed that all of the data is still in the archive file.
3) Delete the user account in outlook
4) Exit outlook and then restart outlook
5) Create a new user account in Outlook. test and send message
6) Exit outlook and then restart outlook, confirmed that the account still works.
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