No, no response yet. Apparently I'm out of support tickets and I'm not going to pay to ask a question about how their software works. I thought this is what the forums are for, and am quite disappointed that no one from Smartertools has responded.
You can set smarthosts by message priority I believe, so perhaps set a smarthost for priority 8 and set the domains that you want to use that smarthost to send all their emails via priority 8. This is the only workaround I can see, but I haven't had time to test it yet.