Hello TD8net; I believe this scenario you outlined should be covered by our authentication settings. In the domain's settings you'll find a toggle to require SMTP authentication, then within Settings>Protocols>SMTP In you'll find similar settings including one called Require Auth Match setting which you can configure for Email Address and that will force the user to authenticate with whichever account they're trying to send from.
Kyle Kerst
IT Coordinator
SmarterTools Inc.
www.smartertools.com