Typically port 465 was always associated with SSL, so I believe it's deprecation means that 587 (with STARTTLS) should be used in its place. Whether or not you disable SSL functionality will depend on your users and which protocols they support. Messages going into the junk email folder on third-party providers could be happening for a variety of reasons unfortunately - if you click on ...>Show Original on the received message in Google - do you see it failing any spam checks?
Kyle Kerst
IT Coordinator
SmarterTools Inc.
www.smartertools.com