Sanidin,
You can use the svcUserAdmin.asmx web service and call GetRequestedUserSettings and SetRequestedUserSettings methods. There are two properties that can be set isenabled (true / false) and enabledstatus (enabled / disabled / disabledwmail).
For enabledstatus:
- disabledwmail will disable the user's web interface access but the account still receives mail;
- disabled disables the user's account;
- enabled enables the user's account
I hope this helps.